Controlled Uniform Coating from the Interplay of Marangoni Flows and Surface-Adsorbed Macromolecules.

TitleControlled Uniform Coating from the Interplay of Marangoni Flows and Surface-Adsorbed Macromolecules.
Publication TypeJournal Article
Year of Publication2016
AuthorsKim, H, Boulogne, F, Um, E, Jacobi, I, Button, E, Stone, HA
JournalPhys Rev Lett
Volume116
Issue12
Pagination124501
Date Published2016 Mar 25
ISSN1079-7114
Abstract

Surface coatings and patterning technologies are essential for various physicochemical applications. In this Letter, we describe key parameters to achieve uniform particle coatings from binary solutions. First, multiple sequential Marangoni flows, set by solute and surfactant simultaneously, prevent nonuniform particle distributions and continuously mix suspended materials during droplet evaporation. Second, we show the importance of particle-surface interactions that can be established by surface-adsorbed macromolecules. To achieve a uniform deposit in a binary mixture, a small concentration of surfactant and surface-adsorbed polymer (0.05 wt% each) is sufficient, which offers a new physicochemical avenue for control of coatings.

DOI10.1103/PhysRevLett.116.124501
Alternate JournalPhys. Rev. Lett.
PubMed ID27058080